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Molybdenum(III) chloride
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Molybdenum(III) chloride : ウィキペディア英語版
Molybdenum(III) chloride

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Molybdenum(III) chloride is the inorganic compound with the formula MoCl3.
==Synthesis and Structure==
The chemical formula of molybdenum trichloride is MoCl3. Molybdenum trichloride is synthesized by the reduction of molybdenum pentachloride with hydrogen. The greatest yield is instead produced by the reduction of pure molybdenum (V) chloride, using anhydrous tin (II) chloride as a reducing agent. This procedure must be performed under a moisture-free and oxygen-free atmosphere of prepurified nitrogen. There are two structures of molybdenum trichloride- alpha (α) and beta (β). The alpha structure is similar to that of aluminum chloride (AlCl3). In this structure, molybdenum has octahedral coordination geometry and exhibits cubic close packing in its crystalline structure. The beta structure, however, exhibits hexagonal close packing.

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